Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher.
Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?
Some links on this page may take you to non-federal websites. Their policies may differ from this site.
-
As the demand for sustainable and efficient water treatment solutions grows, the integration of advanced nanomaterials has become a focal point in enhancing membrane technologies. The purpose of this review is to provide a comprehensive and critical analysis of the current state of research on Ti3C2Tx MXenes, highlighting their unique properties, the challenges they address, and the potential they hold for MXene-enhanced biofiltration-membrane systems. The perspective systematically examines how Ti3C2Tx MXenes, with their exceptional electrical conductivity, hydrophilicity, and tunable surface chemistry, can be integrated into biofiltration-membrane systems to improve key performance metrics such as water flux, contaminant rejection, and fouling resistance. Various processes, including biofiltration, adsorption, and nanofiltration, are discussed, where Ti3C2Tx MXenes have been shown to have a potential application. In addition to synthesizing existing literature, experimental validations are presented that demonstrate how MXene incorporation can alter membrane morphology and structure, leading to improved antibacterial properties and enhanced overall performance. These findings underscore the transformative potential of Ti3C2Tx MXenes in developing next-generation biofiltration-membrane technologies that are not only more efficient but also more sustainable. Through this perspective, the key challenges that remain, such as cost implications and long-term stability, are identified, and future research directions are proposed to address these issues. This in-depth analysis highlights the critical role MXenes can play in advancing water treatment technologies, particularly in the context of water reuse, and encourages further interdisciplinary research in this rapidly evolving field.more » « less
-
Abstract Multiple principal element or high-entropy materials have recently been studied in the two-dimensional (2D) materials phase space. These promising classes of materials combine the unique behavior of solid-solution and entropy-stabilized systems with high aspect ratios and atomically thin characteristics of 2D materials. The current experimental space of these materials includes 2D transition metal oxides, carbides/carbonitrides/nitrides (MXenes), dichalcogenides, and hydrotalcites. However, high-entropy 2D materials have the potential to expand into other types, such as 2D metal-organic frameworks, 2D transition metal carbo-chalcogenides, and 2D transition metal borides (MBenes). Here, we discuss the entropy stabilization from bulk to 2D systems, the effects of disordered multi-valent elements on lattice distortion and local electronic structures and elucidate how these local changes influence the catalytic and electrochemical behavior of these 2D high-entropy materials. We also provide a perspective on 2D high-entropy materials research and its challenges and discuss the importance of this emerging field of nanomaterials in designing tunable compositions with unique electronic structures for energy, catalytic, electronic, and structural applications.more » « less
-
null (Ed.)MXene/polymer nanocomposites simultaneously benefit from the attractive properties of MXenes and the flexibility and facile processability of polymers. These composites have shown superior properties such as high light-to-heat conversion, excellent electromagnetic interference shielding, and high charge storage, compared to other nanocomposites. They have applications in chemical, materials, electrical, environmental, mechanical, and biomedical engineering as well as medicine. This property-based review on MXene/polymer nanocomposites critically describes findings and achievements in these areas and puts future research directions into perspective. It surveys novel reported applications of MXene-based polymeric nanocomposites. It also covers surface modification approaches that expand the applications of MXenes in nanocomposites.more » « less
-
Abstract To advance the MXene field, it is crucial to optimize each step of the synthesis process and create a detailed, systematic guide for synthesizing high‐quality MXene that can be consistently reproduced. In this study, a detailed guide is provided for an optimized synthesis of titanium carbide (Ti3C2Tx) MXene using a mixture of hydrofluoric and hydrochloric acids for the selective etching of the stoichimetric‐Ti3AlC2MAX phase and delamination of the etched multilayered Ti3C2TxMXene using lithium chloride at 65 °C for 1 h with argon bubbling. The effect of different synthesis variables is investigated, including the stoichiometry of the mixed powders to synthesize Ti3AlC2, pre‐etch impurity removal conditions, selective etching, storage, and drying of MXene multilayer powder, and the subsequent delamination conditions. The synthesis yield and the MXene film electrical conductivity are used as the two parameters to evaluate the MXene quality. Also the MXenes are characterized with scanning electron microscopy, x‐ray diffraction, atomic force microscopy, and ellipsometry. The Ti3C2Txfilm made via the optimized method shows electrical conductivity as high as ≈21,000 S/cm with a synthesis yield of up to 38 %. A detailed protocol is also provided for the Ti3C2TxMXene synthesis as the supporting information for this study.more » « less
An official website of the United States government
